"Stronger Than Diamonds" Carbon Nanostructure Designed

By University of California - IrvineApril 14, 2020

With wall thicknesses of about 160 nanometers, a closed-cell, plate-based nanolattice structure designed by researchers at UCI and other institutions is the first experimental verification that such arrangements reach the theorized limits of strength and stiffness in porous materials. Credit: Cameron Crook and Jens Bauer / UCI

Researchers at the University of California, Irvine, and other institutions have architecturally designed plate-nanolattices – nanometer-sized carbon structures – that are stronger than diamonds as a ratio of strength to density.

In a recent study in Nature Communications<em>Nature Communications</em> is a peer-reviewed, open-access, multidisciplinary, scientific journal published by Nature Portfolio. It covers the natural sciences, including physics, biology, chemistry, medicine, and earth sciences. It began publishing in 2010 and has editorial offices in London, Berlin, New York City, and Shanghai. " data-gt-translate-attributes="[{"attribute":"data-cmtooltip", "format":"html"}]">Nature Communications, the scientists report success in conceptualizing and fabricating the material, which consists of closely connected, closed-cell plates instead of the cylindrical trusses common in such structures over the past few decades.

"Previous beam-based designs, while of great interest, had not been so efficient in terms of mechanical properties," said corresponding author Jens Bauer, a UCI researcher in mechanical & aerospace engineering. "This new class of plate-nanolattices that we’ve created is dramatically stronger and stiffer than the best beam-nanolattices."

According to the paper, the team's design has been shown to improve on the average performance of cylindrical beam-based architectures by up to 639 percent in strength and 522 percent in rigidity.

Members of the architected materials laboratory of Lorenzo Valdevit, UCI professor of materials science & engineering as well as mechanical & aerospace engineering, verified their findings using a scanning electron microscope and other technologies provided by the Irvine Materials Research Institute.

"Scientists have predicted that nanolattices arranged in a plate-based design would be incredibly strong," said lead author Cameron Crook, a UCI graduate student in materials science & engineering. "But the difficulty in manufacturing structures this way meant that the theory was never proven, until we succeeded in doing it."

Bauer said the team's achievement rests on a complex 3D laser printing process called two-photonA photon is a particle of light. It is the basic unit of light and other electromagnetic radiation, and is responsible for the electromagnetic force, one of the four fundamental forces of nature. Photons have no mass, but they do have energy and momentum. They travel at the speed of light in a vacuum, and can have different wavelengths, which correspond to different colors of light. Photons can also have different energies, which correspond to different frequencies of light." data-gt-translate-attributes="[{"attribute":"data-cmtooltip", "format":"html"}]">photon polymerization direct laser writing. As a laser is focused inside a droplet of an ultraviolet-light-sensitive liquid resin, the material becomes a solid polymer where molecules are simultaneously hit by two photons. By scanning the laser or moving the stage in three dimensions, the technique is able to render periodic arrangements of cells, each consisting of assemblies of plates as thin as 160 nanometers.

One of the group's innovations was to include tiny holes in the plates that could be used to remove excess resin from the finished material. As a final step, the lattices go through pyrolysis, in which they’re heated to 900 degrees CelsiusThe Celsius scale, also known as the centigrade scale, is a temperature scale named after the Swedish astronomer Anders Celsius. In the Celsius scale, 0 °C is the freezing point of water and 100 °C is the boiling point of water at 1 atm pressure." data-gt-translate-attributes="[{"attribute":"data-cmtooltip", "format":"html"}]">Celsius in a vacuum for one hour. According to Bauer, the end result is a cube-shaped lattice of glassy carbon that has the highest strength scientists ever thought possible for such a porous material.

Bauer said that another goal and accomplishment of the study was to exploit the innate mechanical effects of the base substances. "As you take any piece of material and dramatically decrease its size down to 100 nanometers, it approaches a theoretical crystal with no pores or cracks. Reducing these flaws increases the system's overall strength," he said.

Valdevit, who directs UCI's Institute for Design and Manufacturing Innovation, added, "While the theoretical performance of these structures had been predicted before, we were the first group to experimentally validate that they could perform as well as predicted, while also demonstrating an architected material of unprecedented mechanical performance."

Nanolattices hold great promise for structural engineers, particularly in aerospace, because it's hoped that their combination of strength and low mass density will greatly enhance aircraft and spacecraft performance.

Reference: "Plate-nanolattices at the theoretical limit of stiffness and strength" by Cameron Crook, Jens Bauer, Anna Guell Izard, Cristine Santos de Oliveira, Juliana Martins de Souza e Silva, Jonathan B. Berger and Lorenzo Valdevit, 14 April 2020, Nature Communications.DOI: 10.1038/s41467-020-15434-2

Other co-authors on the study were Anna Guell Izard, a UCI graduate student in mechanical & aerospace engineering, and researchers from UC Santa Barbara and Germany's Martin Luther University of Halle-Wittenberg. The project was funded by the Office of Naval Research and the German Research Foundation.